THE SYNTHESIS AND X-RAY CRYSTAL STRUCTURE STUDIES OF (DI-3-INDOL YL )M ETH YLFERROCENE

• 出 处: 结构化学
• 发表日期: 1993年02期
• 关键词: triclinic belongs condensation catalyzed indole heating substituent allowed ring

A novel anhydrous zinc chloride catalyzed condensation reaction of ferrocenealdehyde with indole in solid state gave the title compound (Di-3-indolyl) methylferrocene ((C8H6N)2CHC5H4FeC5H5) selectively, and its crystal structure has been determined by X-ray diffraction analysis. The crystal belongs to triclinic system, space group P1, with cell parameters a = 9. 624(2), b = 9. 957(2), c=11. 295 (4)A,α=92. 17(2), β=92. 23(2), γ=111. 30(1)°, V=985. 4A3, Mr = 430. 33, Z = 2, Dx = 1. 44g/cm3,μ= 7. 8cm-1, F(000) = 444. The final R = 0. 056 for 3027 observed reflections.

A novel anhydrous zinc chloride catalyzed condensation reaction of ferrocenealdehyde with indole in solid state gave the title compound (Di-3-indolyl) methylferrocene ((C8H6N) 2CHC5H4FeC5H5) selectively, and its crystal structure has been determined by X-ray diffraction analysis. (2), b = 9. 957 (2), c = 11.295 (4) A, α = 92.17 (2), β = 92. 23 (2), γ = 111. 30 (1) °, V = 985. 4A3, Mr = 430. 33, Z = 2, Dx = 1. 44g / cm3, μ = , F (000) = 444. The final R = 0. 056 for 3027 observed reflections.