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Electrophysical properties of multicomponent system Zn2TiO4–Zn2ZrO4–ZnFe2O4 were investigated. The electrical conductivity, band gap, dielectric permittivity, and molar polarizability of formed solid solutions –Zn2-x(TiaZrb)1-xFe2xO4 (x = 0 - 1.0 are defi