A new class of chiral pyrrolidine ligands for homogeneous catalytic enantioselective cyclopropanatio

• 作 者: 施敏 蒋建康
• 机 构: Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of
• 出 处: Chinese Journal of Chemistry
• 发表日期: 2000年03期
• 关键词: pyrrolidine chiral styrene cyclo bidentate have excess moiety duets induction

A new class of chiral pyrrolidine ligands have been successfully synthesized and their chiral induction abilities have been examined in the homogeneous catalytic enantioselective cyclo-propanation of styrene. 15-30% enantiomeric excess ( ee) has been achieved.

A new class of chiral pyrrolidine ligands have been successfully synthesized and their chiral induction abilities have been examined in the homogeneous catalytic enantioselective cyclo-propanation of styrene. 15-30% enantiomeric excess (ee) has been achieved.