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We numerically investigate the coupling of TE-like modes and TM-fike modes in a two-dimensional (2D) photonic crystal (PC) slab composed of truncated cone silicon rods. In such structures, the classification of TE-like modes and TM-like modes is generally impossible and the coupling occurs due to vertical structural asymmetries. The frequency and wavevector dependences of the mode coupling are discussed by investigating the photonic band structures, and the coupling effciency is studied by examining the transmittance. The results show that the efficiency of mode conversion is strengthened by the vertical asymmetry and weakened by the clear small gap. These structures could be used as polarization conversion devices in integrated optics.