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Reaction of Zn(NO3)2.6H2O with 3-(4-carboxylphenylamino)-1-ferrocenyl-2-butylen-1-one (HL) and 4,4-bipyridine (4,4-bipy) in methanol solution resulted in a novel ladder-like coordination polymer {[Zn2L2(μ2-L)2(4,4-bipy)2].MeOH}n (1). Its crystal structure, thermal and electrochemical properties axe presented.