Electrodeposited NiSe_2 on carbon fiber cloth as a flexible electrode for high-performance supercapa

来源 :Journal of Energy Chemistry | 被引量 : 0次 | 上传用户:bianyuantuifei
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A flexible electrode of nickel diselenide/carbon fiber cloth(NiSe_2/CFC) is fabricated at room temperature by a simple and efficient electrodeposition method. Owing to NiSe_2 character of nanostructure and high conductivity, the as-synthesized electrodes possess perfect pseudocapacitive property with high specific capacitance and excellent rate capability. In three-electrode system, the electrode specific capacitance of the NiSe_2/CFC electrode varies from 1058 F g~(-1) to 996.3 F g~(-1) at 2 A g~(-1) to 10 A g~(-1) respectively, which shows great rate capability. Moreover, the NiSe_2 electrode is assembled with an active carbon(AC) electrode to form an asymmetric supercapacitor with an extended potential window of 1.6 V. The asymmetric supercapacitor possesses an excellent energy density 32.7 Wh kg~(-1) with a power density 800 W kg~(-1) at the current density of 1 A g~(-1). The nanosheet array on carbon fiber cloth with high flexibility, specific capacitance and rate capacitance render the NiSe_2 to be regarded as the promising material for the high performance superconductor. Owing to NiSe_2 characterization of nanostructure and high conductivity, the as-synthesized electrodes possess perfect pseudocapacitive property with high specific capacitance and excellent rate capability. In three-electrode system, the electrode specific capacitance of the NiSe_2 / CFC electrode varies from 1058 F g -1 to 996.3 F g -1 at 2 A g -1. the NiSe_2 electrode is assembled with an active carbon (AC) electrode to form an asymmetric supercapacitor with an extended potential window of 1.6 V. The asymmetric supercapacitor possesses an excellent energy density of 32.7 Wh kg -1 with a power density of 800 W kg -1 at the current density of 1 A g -1. The nanosheet array on carbon fiber cloth with high flexibility, specific capacitance and rate capacitance rend er the NiSe_2 to be viewed as the promising material for the high performance superconductor.
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