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The title compounds (4-NH2C6H4S)4Sn 1 and [(4-NH2C6H4S)2(4-NH3C6H4S)2-Sn]Cl2 2 have been synthesized and their crystal structures were determined by X-ray diffraction study. 1 crystallizes in monoclinic, space group P21/m, a = 8.8431 (6), b = 15.2944(10),