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近年来,过渡金属硫化物插层化学应用,得到持续发展,由基体-客体合成的插层包合物具有的独特性质带来的广阔应用前景,引发了研究人员极大兴趣。MoS2,是过渡金属硫化物中的一员,在插层化学方面的研究刚刚起步,研究发现其良好的层状结构使得MoS2非常适合用作插层化学基体。且不管是基体MoS2还是插层包合物MoS2所表现出来润滑及催化特性,都关联于材料的电子能带结构及层状结构所包含的范德华层间空域。在此基础上,本文将对MoS2的结构性质、MoS2插层包合物的合成应用等方面作介绍分析。
In recent years, the transition metal sulfide intercalation chemistry applications, sustained development, from the substrate - guest synthesis of intercalated inclusion complex has broad application prospects, has aroused great interest of researchers. MoS2, a member of transition metal sulfides, has just started its research on intercalation chemistry and found that its good layered structure makes MoS2 well suited as an intercalation chemical matrix. The lubrication and catalytic properties of MoS2 and intercalated inclusion MoS2 are both related to the electronic energy band structure and van der Waals interlayer space contained in the layered structure. On this basis, this article will analyze the structural properties of MoS2, the synthesis and application of MoS2 intercalated inclusion complexes.