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自20世纪70年代导电聚合物发现以来,聚吡咯、聚苯胺、聚噻吩、聚(3,4-乙撑二氧噻吩)、聚对苯及其衍生物等,以其特殊的电子、电化学、光学性质以及巨大应用潜力受到广泛关注。离子液体是一类在室温或接近室温时呈液态的离子化合物,作为一类环境友好的新型绿色溶剂,具有很多独特的物理化学性质。本文综述了离子液体作为反应介质、支持电解质、测试介质以及离子液体参与形成的聚集体,在导电聚合物的电化学合成以及电化学性质测试中的研究进展,并展望了发展趋势。
Since the discovery of conducting polymers in the 1970s, polypyrrole, polyaniline, polythiophene, poly (3,4-ethylenedioxythiophene), polyparaphenylene and its derivatives, etc. have been widely used in the fields of their special electronic and electrochemical , Optical properties and great potential for application have received widespread attention. Ionic liquids are a class of ionic compounds that are liquid at or near room temperature and have many unique physicochemical properties as a class of environmentally friendly new green solvents. This review summarizes the research progress of ionic liquids as reaction medium, supporting electrolytes, test media and ionic liquids involved in the formation of aggregates, electrochemical synthesis of electrochemical and electrochemical properties of conductive polymers, and prospects for the development trend.