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The nature of bonding in the title compounds has been studied by using CASSCF and FOCI techniques. The ground states of PtC and PtN are found to be 1(+ and 2( state arising primarily from:...1(22(21(41(43(2 and ...1(22(21(41(43(22π1 configuration respectively and both of which form triple bond (one (, twoπbonds), but the bond of PtC is much stronger than that of PtN.
The nature of bonding in the title compounds has been studied by using CASSCF and FOCI techniques. The ground states of PtC and PtN are found to be 1 (+ and 2 (state inquiries: 1 (22 (21 (41 (43 (2 (21 (41 (22 (41 (41 (43 (22 (41