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The isothermal and cyclic oxidizing kinetics of Co-40Cr alloy and its lanthanum ion-implanted samples were studied at 1 000 ℃ in air by thermal gravimetric analysis(TGA).Scanning electron microscopy(SEM)was used to examine the Cr2O3 oxide film’s morphology after oxidation.Secondary ion mass spectrum(SIMS)method was used to examine the binding energy change of chromium caused by La-doping and its influence on the formation of Cr2O3 film.Acoustic emission(AE)method was used in situ to monitor the cracking and spalling of oxide films during oxidizing and subsequent air-cooling stages.Laser Raman spectrum was used to examine the stress changes within oxide films.A theoretical model was proposed relating to the film fracture process and was used to analyze the AE spectrum both on time domain and AE-event number domain.It was found that lanthanum implantation remarkably reduced the isothermal oxidizing rate of Co-40Cr and improved the anti-cracking and anti-spalling properties of Cr2O3 oxide film.The reasons for the improvement were mainly that the implanted lanthanum reduced the grain size and internal stress of Cr2O3 oxide,increased the high temperature plasticity of oxide film,and remarkably reduced the number and size of Cr2O3/Co-40Cr interfacial defects.
The isothermal and cyclic oxidizing kinetics of Co-40Cr alloy and its lanthanum ion-implanted samples were studied at 1 000 ° C in air by thermal gravimetric analysis (TGA). Scanning electron microscopy (SEM) was used to examine the Cr2O3 oxide film’s morphology after oxidation. Secondary ion mass spectrum (SIMS) method was used to examine the binding energy change of chromium caused by La-doping and its influence on the formation of Cr2O3 film. Acoustic emission (AE) method was used in situ to monitor the cracking and A theoretical model was proposed relating to the film fracture process and was used to analyze the AE spectrum both on time domain and AE-event number domain. It was found that lanthanum implantation remarkably reduced the isothermal oxidizing rate of Co-40Cr and improved the anti-cracking and anti-spalling properties of Cr2O3 oxi de film. The reasons for the improvement were mainly that the implanted lanthanum reduced the grain size and internal stress of Cr2O3 oxide, increased the high temperature plasticity of oxide film, and remarkably reduced the number and size of Cr2O3 / Co-40Cr interfacial defects.