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SDS/BA/H_2O体系电导率、反离子缔合度和电容测定表明:在O/W微乳液区域,电导率、反离子缔合度和电容值都较小;在恒定m(SDS)/m(H_2O)下,随着BA含量的增加,电导率、反离子缔合度和电容值先增加,达到一最大值后又逐渐下降.在双连续区域,为链式导电机理,电导率、反离子缔合度、电阻和电容值几乎不随水含量变化.根据加权最小二乘法回归,O/W球形胶束区域的电容值与各物理化学特性数值(κ,β,N,D,ε,χ)的关系为:C/μF=1.036×10~(-8)(1-β)Z_sκD~(-1)+0.03466ε_1χ_1-0.09677ε_2χ_2.
SDS / BA / H 2 O system conductivity, the degree of counter-ion association and capacitance measurements show that: in the O / W microemulsion region, the conductivity, the counter ion association and capacitance values are small; ), With the increase of BA content, the conductivities, the counter-ion association degree and the capacitance value first increase and reach a maximum value and then decrease gradually.In the double continuous region, the mechanism of chain conduction, conductivity, , The values of resistance and capacitance hardly change with the water content.According to the weighted least squares regression, the relationship between the capacitance of O / W spherical micelles and the values of the physicochemical properties (κ, β, N, D, ε, χ) is : C / μF = 1.036 × 10 ~ (-8) (1-β) Z_sκD ~ (-1) + 0.03466ε_1χ_1-0.09677ε_2χ_2.