Preparation and characterization of La_(0.8)Sr_(0.04)Ca_(0.16)Co_(0.6)Fe_(0.4)O_(3-δ)-La_(0.9)Sr_(0.

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:tshy65655
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The La0.8Sr0.04Ca0.16Co0.6Fe0.4O3-δ (LSCCoF) and La0.9Sr0.1Ga0.8Mg0.2O3 (LSGM) powders were synthesized by glycine-nitrate combustion process and conventional solid-state reaction method, respectively. The LSCCoF-LSGM composite cathode material was successfully elaborated and deposited on dense pellets of the LSGM electrolyte by means of slurry spin-coating process. The cathode films with the best surface morphology and microstructure were obtained when the operating parameters fixed as follows: the content of ethyl cellulose which acted as pore former and binder is 10 wt.%, the content of terpineol which acted as modifier is 5 wt.%, the speed of rotation rate is 3200 r/min and the best post-deposition sintering temperature is 1000°C. The La0.8Sr0.04Ca0.16Co0.6Fe0.4O3-δ (LSCCoF) and La0.9Sr0.1Ga0.8Mg0.2O3 (LSGM) powders were synthesized by glycine-nitrate combustion process and conventional solid-state reaction method, respectively. The LSCCoF-LSGM composite cathode material was successfully elaborated and deposited on dense pellets of the LSGM electrolyte by means of slurry spin-coating process. The cathode films with the best surface morphology and microstructure were obtained when the operating parameters fixed as follows: the content of ethyl cellulose which acted as pore former and binder is 10 wt.%, the content of terpineol which acted as modifier is 5 wt.%, the speed of rotation rate is 3200 r / min and the best post-deposition sintering temperature is 1000 ° C.
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