用T-jump/FTIR研究MnCP、NiCP和PbCP的快速热分解(英文)

• 作 者: 孙远华 张同来 张建国
• 机 构: 爆炸灾害预防与控制国家重点实验室北京理工大学,爆炸灾害预防与控制国家重点实验室北京理工大学,爆炸灾害预防与控制国家重点实验室北京理工大学 北京100081,北京100081,北京100081
• 出 处: 无机化学学报
• 发表日期: 2005年01期
• 关键词: 热分解 碳酰肼配合物 碳酰肼 T-jump/FTIR carbo 英文 无机化学学报 petroleum 快速热分解

ClO4)2 (MnCP),(ClO4)2 (NiCP) and (ClO4) 2 (PbCP) (CHZ=Carbohydrazide) were flash pyrolyzed at different temperatures und er the set pressure by T-jump/FTIR spectroscopy. The results show that twelve ga s products obtained during the flash pyrolysis process of the three complexes we re CO2, CO, HCl, HCN, NH3, NO2, N2O, NO, HNCO, HONO, H2C=O and H2O, of which CO2 , HCN and HCl were the main gas products and CO2 was the most novel product. NH3 was oxidized to NO2, N2O and H2O. At least some of the N2O might result from th is reaction. Additionally, the effect of temperature on the gas products is disc ussed and the concentration-time change curves of the main gas products are give n.

The result show that that was flash pyrolyzed at different temperatures and er er the set pressure by T-jump / FTIR spectroscopy. twelve ga s products obtained during the flash pyrolysis process of the three complexes we re CO2, CO, HCl, HCN, NH3, NO2, N2O, NO, HNCO, HONO, H2C = O and H2O, of which CO2, HCN and HCl were The main gas products and CO2 was the most novel product. NH3 was oxidized to NO2, N2O and H2O. At least some of the N2O might result from th is reaction. Additionally, the effect of temperature on the gas products is disc ussed and the concentration-time change curves of the main gas products are give n.