用Mo(Ⅲ)络合物分裂N_2分子麻省理工学院的C.E.Laplaza和C.C.Cummins用配位数为3的Mot(Ⅲ)络合物Mo(NRAr)3[R=C(CD3)2CH3;Ar=3,5-C6H3Me2(Me,-CH3)与N2反应,实现了将N2分子裂开还?..
Disintegration of N_2 Molecule with Mo (Ⅲ) Complexes. E. Laplaza and C. C.
In this paper, photorefractive crystals of Cu-doped (K0.5Na0.5)0.2 (Sr0.75Ba0.25)0.9Nb2O6 (KNSBN) are systematically studied. A series of Cu-doped KNSBN crystal