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一、引言近二十年来,现代电化学技术不仅应用到有机合成,并已成功地应用于工业生产,如丙烯腈电解还原二聚可生产己二腈(尼龙66的原料),四乙基铅的电化合成等。电化法的优点是不带来环境污染,也比较经济。此外,有机化合物通过电极反应可以形成许多活性中间体(见表1),为研究这些活性中间体的化学提供了方便的途径(例如电解槽可直接置于顺磁共振仪的共振腔中),并且也提供进行一些特殊反应的方法。
I. INTRODUCTION In the recent two decades, modern electrochemical technology has been applied not only to organic synthesis but also to industrial production successfully. For example, acrylonitrile electrolytic reduction dimerization can produce adiponitrile (raw material of nylon 66), tetraethyl lead The electrochemical synthesis. The advantages of electrochemical method is not to bring environmental pollution, but also more economical. In addition, organic compounds can form many active intermediates by electrode reaction (see Table 1), providing a convenient way to study the chemistry of these active intermediates (eg electrolyzer can be placed directly in the para resonance resonator) And also provide some special reaction method.