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对复杂混合物中未知组分的定性鉴定是气相色谱(GC)分析的艰巨而重要的任务。GC定性方法很多,其中用Kovats指数值(I_R)定性,提高了定性数据的准确度。近年来很多色谱工作者把化合物的I_R与其物理性质、分子结构进行关联,对预测化合物I_R值提供了方便。我们在研究有机氮化合物的金属络合物新反应中,测
The qualitative identification of unknown components in complex mixtures is a daunting and important task for gas chromatography (GC) analysis. There are many qualitative methods of GC, among which qualitative Kovats index (I_R) is used to improve the accuracy of qualitative data. In recent years, many chromatographers associate the I_R of a compound with its physical properties and molecular structure to facilitate the prediction of the I_R value of a compound. We are investigating novel reactions of organo-nitrogen compounds in metal complexes