磷酰化与非磷酰化蛋氨酸水溶液的脉冲辐解研究

来源 :物理化学学报 | 被引量 : 0次 | 上传用户:wei_357
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OH redical induced oxidation of methionine and N-phosphoryl methioninein aqueous solutions has been investigated using optical pulse radiolytical technique, theinfluence of N-phosphoryl group on the radiolytical processes of methionine has beenexplained by molecular structure and the rate constants of oxidation of N-phosphoryl methionine (NDM) by the OH radicals at different pH values have been determined. Thisresearch result suggests that the phosphonate ester has a coordinating effect on the radioprotection of methionine to the biological systems. OH redical induced oxidation of methionine and N-phosphoryl methionine in aqueous solutions has been investigated using an optical pulse radiolytical technique, the fluid of N-phosphoryl group on the radiolytical processes of methionine has beenexplained by molecular structure and the rate constants of oxidation of N-phosphoryl methionine (NDM) by the OH radicals at different pH values ​​have been determined. This research suggests suggests that the phosphonate ester has a coordinating effect on the radioprotection of methionine to the biological systems.
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