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In situ energy dispersive x-ray diffraction for natural marmatite (Zn0.76Fe0.23S) is performed up to 17.7 GPa and 623K. It is fitted by the Birch-Muaghan equation of state (EOS) that K0 and α0 for marmatite are 85(3)GPa and 0. 79(16)× 10-4 K-1, respectively.