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A new dinuclear copper(Ⅱ) complex ([Cu(C12H17N2O)(N3)]2, C24H34Cu2N10O2) has been synthesized and characterized by X-ray structure determination. It crystallizes in the monoclinic system, space group P2t/C with α = 18.529(4), b = 10.933(2), c=14.534(3)A,