Oxidation of alkybenzenes PhCH_2R(R=H, CH_3, C_2H_5 and n-C_3H_7) under 1 atm. of O_2 or air catalyzed by iron(Ⅱ, Ⅲ)-2,2’-bipyridine and 1,10-phenanthroline
催化脱去烯丙基酯保护基ChavanSP等[TetrahedronLett,1996;37:237]羧酸烯丙基酯和苯甲醚,在硫酸化SnO2的作用下,在甲苯中于110℃搅拌2~12h,可选择性脱去烯丙基,得羧酸。底物中的甲酯不受影响,14例产率50%~9...
Catalytic removal of allyl