Rhodium-Catalyzed Asymmetric Reactions Using Self-Assembled Chiral Bidentate Ligands

• 作 者: Kittichai Chaiseeda Shin A. Mo
• 机 构: Department of Chemistry
• 出 处: 复旦学报（自然科学版）
• 发表日期: 2004年期
• 关键词: self-assembly asymmetric catalysis chiral ligands rhodium catalyst
• 基金项目: the NSF;NIH

1 IntroductionWe recently described a new combinatorial strategy for modular catalyst development, one using self-assembly in the ligand scaffold-generating step to produce libraries of chiral self-assembled ligands. Metal-directed self-assembly of bifunctional subunits around a structural metal (typically zinc) can be used to form a heteroleptic complex in which a second set of ligating groups are suitably disposed to form a heterobimetallic catalyst system[1]. See Fig. 1