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Hydrated potassium monoborate(KBO 2 ·4/3H 2 O)was obtained from an aqueous solutio n in a mole ratio of K 2 O∶B 2 O 3 =2∶1and characterized by powder X-ray diffraction(XRD),infrared spectroscopy(FT-IR)and Raman spectroscopy.The enthalpy of solut ion of hydrated potassium monoborate,KBO 2 ·4/3H 2 O,in approximately1mol·dm -3 aqueous hydrochloric acid was determined.Together with the previously determined enthalpies of so-lution of H 3 BO 3 in approximately 1mol·dm -3 HCl (aq),and of KCl in aqueous(hydrochloric acid +boric acid),the standard molar enthalpy of forma tion of -(1411.11±0.84)kJ·mol -1 for KBO 2 ·4/3H 2 O was obtained from the standard molar enthalpies of formation of KCl (s),H 3 BO 3 (s),and H 2 O(l).The standard molar entropy of formation of -422.94J ·K -1 ·mol -1 and standard molar entropy of 163.47J·K -1 ·mol -1 for KBO 2 ·4/3H 2 O were calculated from the thermodynamic relations.A group contribution method is applicable to KBO 2 ·4/3H 2 O.
Hydrated potassium monoborate (KBO 2 · 4 / 3H 2 O) was obtained from an aqueous solutio n in a mole ratio of K 2 O: B 2 O 3 = 2: 1 and characterized by powder X-ray diffraction (XRD) (FT-IR) and Raman spectroscopy. The enthalpy of solute of hydrated potassium monoborate, KBO 2 · 4 / 3H 2 O, in approximately1 mol · dm -3 aqueous hydrochloric acid was determined .Together with the previously determined enthalpies of so-lution of H 3 BO 3 in approximately 1 mol · dm -3 HCl (aq), and of KCl in aqueous (hydrochloric acid + boric acid), the standard molar enthalpy of formation- (1411.11 ± 0.84) kJ · mol -1 for KBO 2 · 4 / 3H 2 O was obtained from the standard molar enthalpies of formation of KCl (s), H 3 BO 3 (s), and H 2 O (1). The standard molar entropy of formation of -422.94 J · K -1 · mol -1 and a standard molar entropy of 163.47 J · K -1 · mol -1 for KBO 2 · 4/3 H 2 O were calculated from the thermodynamic relations.A group contribution method is applicable to KBO 2 · 4 / 3H 2 O.