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本文提出了富烯碳原子簇的石墨层间闭合形成机理,由该机理推出的许多结果与实验事实符合很好。我们认为碳原子簇自由基的快速淬灭及其淬灭速度是富烯碳原子簇形成及其丰度的决定因素。由此得出富烯碳原子簇在给定实验条件下产生的必然性,并预言不同大小的富烯碳原子簇可以通过优化实验条件选择性地合成。
In this paper, the formation mechanism of graphite intercalation between fullerene clusters has been proposed. Many results derived from this mechanism are in good agreement with the experimental results. We think that the rapid quenching and quenching rate of carbon atom cluster free radicals is the decisive factor for the formation and abundance of fullerene clusters. The inevitability of fullerene-rich clusters under the given experimental conditions was obtained, and it was predicted that different sizes of fullerene-rich clusters could be selectively synthesized by optimizing the experimental conditions.