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In this paper,we prove the non-triviality of the product h 0 k o δ s+4 ∈ Ext s+6,t(s) A (Z p ,Z p ) in the classical Adams spectral sequence,where p ≥ 11,0 ≤ s < p-4,t(s) = (s + 4)p 3 q + (s + 3)p 2 q + (s + 4)pq + (s + 3)q + s with q = 2(p-1).The elem