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合成了1个含有取代芳酰腙和单齿N-杂环分子的三元铜配合物[Cu(L)(ampy)](H2L=5-溴水杨醛苯甲酰腙,ampy=2-氨基吡啶),并通过IR、UV、荧光光谱和循环伏安进行了性质研究。[Cu(L)(ampy)]的晶体结构分析表明,中心金属通过酰腙配体的酚基氧原子、亚胺基氮原子、去质子酰胺氧原子以及中性杂环分子的氮原子形成平面四方形的N2O2配位环境。配合物通过N-H…O和N-H…N氢键作用形成一维链状结构。
A ternary copper complex [Cu (L) (ampy)] containing substituted aroyl hydrazones and monodentate N-heterocyclic molecules was synthesized (H2L = 5-bromosalicylaldehyde benzoylhydrazone, ampy = 2- Aminopyridine) and characterized by IR, UV, fluorescence spectroscopy and cyclic voltammetry. Crystal structure analysis of [Cu (L) (ampy)] shows that the central metal forms a plane through the nitrogen atom of the phenolic oxygen atom, the imino nitrogen atom, the deprotonamide oxygen atom and the neutral heterocyclic molecule of the acylhydrazone ligand Square Quadratic N2O2 Coordination Environment. The complex forms a one-dimensional chain structure through N-H ... O and N-H ... N hydrogen bonding.