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Complex [Mn2(C6H11CO2)3(4,4’-bipy)2(H2O)2]ClO4(C6H11CO2H=cyclohexanecarboxylic acid) was synthesized by reaction of Mn(ClO4)2.6H2O,C6H11CO2Na and 4,4’-bipy in methanol.The title complex crystallizes in triclinic space group P1,with a=1.008 8(2) nm,b=1.086 3(1) nm,c=1.164 9(3) nm,α=63.016(3)°,β=81.998(4)°,γ=88.604(1)°,V= 1.125 4(4) nm3,Z=1.There are two types of Mn atoms in the structure with each in octahedral geometry.Mn1 and Mn2 are bridged by cyclohexanecarboxylate ligands into a chain and the chains are further linked together by 4,4’-bipy into a 2D plane.CCDC:692247.
Complex [Mn2 (C6H11CO2) 3 (4,4’-bipy) 2 (H2O) 2] ClO4 (C6H11CO2H = cyclohexanecarboxylic acid) was synthesized by reaction of Mn (ClO4) 2.6H2O, C6H11CO2Na and 4,4’-bipy in methanol The title complex crystallizes in a triclinic space group P1 with a = 1.008 8 (2) nm, b = 1.086 3 (1) nm, c = 1.164 9 (3) nm, (4) °, γ = 88.604 (1) °, V = 1.125 4 (4) nm3, Z = 1. There are two types of Mn atoms in the structure with each in octahedral geometry. Mn1 and Mn2 are bridged by cyclohexanecarboxylate ligands into a chain and the chains are further linked together by 4,4’-bipy into a 2D plane. CCDC: 692247.