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为寻找电子跃迁可见化学激光体系,十几年来几乎对所有可见化学发光反应的机理进行了广泛而深入的研究。然而、Bi+N_2O化学发光反应的研究至今却仍无文献报导。我们对达个反应的化学发光光谱分析得出了52个归属于BiO(A~2Π_(1/2)——X_1~2Π_(1/2))跃迁系的振动谱带,
In order to find out the electronic transition visible chemical laser system, the mechanism of almost all visible chemiluminescence reactions has been extensively studied in more than ten years. However, there is still no literature report on the chemiluminescence reaction of Bi + N 2 O until now. We have obtained 52 vibrational bands belonging to the BiO (A ~ 2Π_ (1/2) - X_1 ~ 2Π_ (1/2)) transition system by chemiluminescence spectroscopy.