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以硝酸铜、4′-(4-甲氧基)-2,2′:6′,2″-三联吡啶、对苯二甲酸为原料,用水热法合成了一种新型的双核Cu配合物[Cu_2(tp)(tripy)_2]·2NO_3,(tp=对苯二甲酸,tripy=4′-(4-甲氧基)-2,2′:6′,2″-三联吡啶),采用IR对其结构进行表征,并用单晶X射线衍射法测得其单晶结构为三斜,空间点群为P-1,晶体学参数为:a=8.677(3),b=10.989(5),c=14.596(5),α=95.552(13)°,β=101.710(8)°,γ=110.948(9)°,V=1250.7(8)~3,Dc=1.572g.cm~(-3),Z=1.
A novel binuclear Cu complex was synthesized by hydrothermal method using cupric nitrate, 4 ’- (4-methoxy) -2,2’: 6 ’, 2 “-terminopyridine and terephthalic acid as raw materials. (Tp) (tripy) _2] · 2NO_3 (tp = terephthalic acid, tripy = 4’- (4-methoxy) -2,2 ’: 6’, 2 ”-terpyridine) Its structure was characterized by single crystal X-ray diffraction and its single crystal structure was triclinic. The spatial point group was P-1. The crystallographic parameters were as follows: a = 8.677 (3) and b = 10.989 (5) c = 14.596 5, α = 95.552 (13) °, β = 101.710 (8) °, γ = 110.948 (9) °, V = 1250.7 (8) ~ 3, Dc = 1.572 g · cm ~ (-3), Z = 1.