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由二苯甲酮-4,4′-二甲酸和邻菲咯啉为配体合成了1个新的镉化合物[Cd(bpndc)(phen)2(H2O)].2H2O(1)(H2bpndc=二苯甲酮-4,4′-二甲酸),并对其进行了元素分析、IR及X-射线衍射法表征。晶体结构表明:配合物1属于四方晶系,I41/a空间群。配合物1中心镉原子是六配位的变形八面体构型,该单核化合物通过氢键拓展成一维链状结构。配合物1的荧光测试研究表明它具有蓝色荧光。
A new cadmium compound [Cd (bpndc) (phen) 2 (H2O)] was synthesized from benzophenone-4,4’-dicarboxylic acid and phenanthroline.2H2O (1) (H2bpndc = Benzophenone-4,4’-dicarboxylic acid), and its elemental analysis, IR and X-ray diffraction characterization. The crystal structure shows that complex 1 belongs to the tetragonal system, and space group I41 / a. The Cd atom in the center of complex 1 is a hexacoordinated deformed octahedral configuration, and the mononuclear compound expands into a one-dimensional chain structure through hydrogen bonding. Fluorescence test of complex 1 showed that it has blue fluorescence.