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基团振动光谱受到复杂的影响，但由氧族元素形成的组成类似，空间构型相同的基团（分子或离子），其振动光谱波数具有规律变化，例外较少。
The vibrational spectra of the radicals are complicatedly affected, but the groups of elements (molecules or ions) that are formed by the oxygen species are similar in structure and have a regular change in the wave number of the vibrational spectrum with few exceptions.