论文部分内容阅读
2.1.5对亚胺,硫代羰基,氰基等的加成下列规则与对羰基的加成的规则相似。实例:1.(?) C-甲基-N-碘代镁-加成 (C-methyl-N-iodomagnesio-addition)2.PhNO十PhLi→Ph_2NOLi O-锂-N-苯基-加成 (O-lithio-N-phenyl-addition)3.2-金刚烷硫酮+2-金刚烷硫醇→双(2-金刚烷基)二硫化合物
2.1.5 Addition to imines, thiocarbonyls, cyano groups, etc. The following rules are similar to the rules for the addition of carbonyl groups. Examples: 1. (?) C-methyl-N-iodomagnesio-addition 2. PhNO n PhLi → Ph_2NOLi O-lithium-N-phenyl- O-lithio-N-phenyl-addition 3.2-adamantanethione + 2-adamantanethiol → bis (2-adamantyl) disulfide