SYNTHESIS AND CHARACTERIZATION OF POLY{4-[2-(tert-BUTYLDIMETHYLSILOXY)ETHYL]STYRENE} AND ITS HYDROLY

• 作 者: Yi-bo Wu Wen-li Guo Shu-xin Li
• 机 构: DepartmentofMaterialScienceandEngineering
• 出 处: 高分子科学：英文版
• 发表日期: 2009年3期
• 关键词: Living carbocationic polymerization Poly[4-(2-hydroxyethyl)styrene] HYDROLYSIS P
• 基金项目: This work was financially supported by the Beijing Municipal Project for Developing Advanced Human Resources for Higher Education (Elastomers and Biomaterials).

The living cationic polymerization of 4-[2-(tert-butyldimethylsiloxy)ethyl]styrene (TBDMES) was studied in methylcyclohexane (MeChx)/methylchloride (MeCI) (50/50 V/V) solvent mixture at -80℃. The initiator 1,1-diphenylethylene (DPE) capped 2-chloro-2,4,4-