A Comparative Study of Hydrophilic Modification of Polypropylene Membranes by Remote and Direct Ar P

来源 :Plasma Science and Technology | 被引量 : 0次 | 上传用户:jin1067061730
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Surface modification of polypropylene membrane by argon (Ar) plasma-inducedgraft polymerization with hydrophilic n, onomer [acrylic acid (AA) in this work] was investigated.It was found that both the distance of the membrane from the Ar plasma center and the plasmapower had a strong influence on the surface modification, hydrophilicity and graft yield (GY)of the treated membrane. Results suggest that remote plasma treatment with a proper sampleposition, plasma power and graft polymerization leads to a membrane surface with not only lessdamage, bnt also more permanent hydrophilicity, than direct plasma treatment does. By analyzingthe morphology and the chemical composition of the membrane surface by scanning electronmicroscopy (SEM) and X-ray photoelectron spectroscopy (XPS), as well as Fourier transform infraredattenuated total reflection spectroscopy (FTIR-ATR) respectively, a possible mechanismwas tentatively revealed. Surface modification of polypropylene membrane by argon (Ar) plasma-inducedgraft polymerization with hydrophilic n, onomer [acrylic acid (AA) in this work] was investigated. It was found that both the distance of the membrane from the Ar plasma center and the plasmapower had a strong influence on the surface modification, hydrophilicity and graft yield (GY) of the treated membrane. Results suggest that remote plasma treatment with a proper sampleposition, plasma power and graft polymerization leads to a membrane surface with not only lessdamage, bnt more By analyzing the morphology and the chemical composition of the membrane surface by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), as well as Fourier transform infrared constant total reflection spectroscopy (FTIR-ATR) respectively, a possible mechanismwas tentatively revealed.
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