Electrical Properties and Applications of (ZrO_2)_(0.92)(Y_2O_3)_(0.08) Electrolyte Thin Wall Tubes

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:alan39
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mole fraction) yttria-stabilized zirconia electrolyte thin wall tubes were p repared by i mproved slip casting method. The length and wall thickness of the tubes are 266 mm and 0.4~0.9 mm, respectively and the relative density is 96.7%. The microstr ucture and electrical properties of samples sintered at different temperatures w ere studied using SEM and ac impedance spectroscopy. The effect of sintered dens ity, grain and grain boundary on the electrical properties of the samples was analyzed. The research results show that the density of the samples increase s gradually with increasing sintering temperatures. The microstructure of sample s strongly influences its electrical properties, and the electrical properti es of samples enhance with the increase of sintered density. The ionic conductiv ity of grain and grain boundary is increased as the sintering temperature incre ases. Better sinterability of the samples was obtained at the sintering temperat ure of 1650 ℃. The maximum open circuit voltage and short circuit current for s ingle cell is 0.946 V and 1.84 A, respectively. The maximum output power of sing le cell is 0.46 W at the temperature of 850 ℃. mole fraction) yttria-stabilized zirconia thin wall tubes were p repared by i mproved slip casting method. The length and wall thickness of the tubes are 266 mm and 0.4 ~ 0.9 mm, respectively and the relative density is 96.7%. The microstr ucture and electrical properties of samples sintered at different temperatures w ere studied using SEM and ac impedance spectroscopy. The effect of sintered dens ity, grain and grain boundary on the electrical properties of the samples was analyzed. The research results show that the density of the samples The microstructure of sample s strongly influences its electrical properties, and the electrical properties of samples enhance with the increase of sintered density. ases. Better sinterability of the samples was obtained at the firing temperat ure of 1650 ° C. The maximum The open circuit voltage and short circuit current for single cell is 0.946 V and 1.84 A, respectively. The maximum output power of sing le cell is 0.46 W at the temperature of 850 ° C.
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