Wetting behavior of AgCu-4.5Ti filler reinforced by carbon nanotubes on C/C composite

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The effect of Carbon Nanotubes (CNTs) content on the wettability of AgCu-4.5Ti +x CNTs (wt%) composite filler alloys on C/C composite was investigated.The results show that the added CNTs reacted with element Ti in the filler and produced the dispersed fine in situ synthe-sized TiC particles,which increased the consumption of element Ti and provided the nucleus for the growth of Ti-Cu compounds simultaneously.The above effects of introducing CNTs,inhibited the formation of Ti-Cu compounds,also changed the distribution of compounds,which dramatically influenced the interfacial microstructure and characteristics of wetting behavior.The increase of CNTs content refined and dispersed coarse Ti-Cu compounds,decreased the initial spreading tem-perature,and improved the wettability,but high content of CNTs (more than 0.3wt%) decreased the wettability of the filler alloy.The wetting interfacial microstructure of corresponding composite filler alloys were analyzed by Scanning Electron Microscope (SEM),Energy Dispersive X-ray Spec-trometer (EDS) and Transmission Electron Microscope (TEM),which consisted of TiC,TiCu,TiCu2 and TiCu4 compound.The typical wetting behavior of AgCu-4.5Ti + 0.3wt% CNTs com-posite filler on C/C composite was divided into four stages.The effect mechanism of CNTs content on the wetting behavior was proposed.
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