【摘 要】
:
The effect of the sintering atmospheres (vacuum, N2, Ar) on the microstructures and properties of the TiC based cermets was studied using XRD, SEM/BSE and energ
【机 构】
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Department of Metallurgy,State Key Laboratory of Powder Metallurgy
【基金项目】
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国家高技术研究发展计划(863计划);Scientific Research Fund of Education Department of Hunan Province
论文部分内容阅读
The effect of the sintering atmospheres (vacuum, N2, Ar) on the microstructures and properties of the TiC based cermets was studied using XRD, SEM/BSE and energy dispersive spectrometer. Compared with the alloy sintered in vacuum, the carbon content of the specimen sintered in N2 and Ar is lower by 0.5%; and the nitrogen content is higher by 0.3% when sintered in nitrogen.The central part of the ring structure may be carbide with either a high W or Ti content. The ring structures are (Ti, W, Ta, Mo, Co,Ni)C solid solutions with different metallic elements and distributions. The composition of the binder phase is (Co, Ni) solid solution with different Ti, W, Ta, Mo, C contents. The structures are uniform for the cermets sintered in vacuum and the properties are the best.When sintered in Ar or N2, the O2 and N2 in the atmosphere take part in the sintering reaction to break the carbon balance in the cermets to form a shell structure and defects, which results in poor density, microhardness (HV) and transverse rupture strength (TRS).
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