Design of Fe_(3–x)O_4 raspberry decorated graphene nanocomposites with high performances in lithium-

来源 :Journal of Energy Chemistry | 被引量 : 0次 | 上传用户:woainami
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Fe_(3–x)O_4 raspberry shaped nanostructures/graphene nanocomposites were synthesized by a one-step polyol-solvothermal method to be tested as electrode materials for Li-ion battery(LIB). Indeed, Fe_(3–x)O_4 raspberry shaped nanostructures consist of original oriented aggregates of Fe_(3–x)O_4 magnetite nanocrystals, ensuring a low oxidation state of magnetite and a hollow and porous structure, which has been easily combined with graphene sheets. The resulting nanocomposite powder displays a very homogeneous spatial distribution of Fe_(3–x)O_4 nanostructures at the surface of the graphene sheets. These original nanostructures and their strong interaction with the graphene sheets resulted in very small capacity fading upon Li+ion intercalation. Reversible capacity, as high as 660 m Ah/g, makes this material promising for anode in Li-ion batteries application. Fe 3-x O 4 raspberry shaped nanostructures / graphene nanocomposites were synthesized by a one-step polyol-solvothermal method to be tested as electrode materials for Li-ion battery (LIB). Indeed, Fe_ (3-x) O_4 raspberry shaped nanostructures consist of original oriented aggregates of Fe_ (3-x) O_4 magnetite nanocrystals, ensuring a low oxidation state of magnetite and a hollow and porous structure, which has been easily combined with graphene sheets. The resulting nanocomposite powder displays a very homogeneous spatial distribution of Fe_ (3-x) O_4 nanostructures at the strong interaction with the graphene sheets resulted in very small capacity fading on Li + ion intercalation. Reversible capacity, as high as 660 m Ah / g, makes this material promising for anode in Li-ion batteries application.
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