【摘 要】
：
Eleven (S)-(-)-bishydrocarbyl-(1-alkanoylpyrrolidin-2-yl)-methanol derivatives of three types were synthesized from L-proline, asymmtrically selective alkylati
【出 处】
：
Chinese Chemical Letters
论文部分内容阅读
Eleven (S)-(-)-bishydrocarbyl-(1-alkanoylpyrrolidin-2-yl)-methanol derivatives of three types were synthesized from L-proline, asymmtrically selective alkylation products were obtained by LDA treatment and alkylation using methyl 2-bromoethyl ether, and three types of chiral α-substituted-γ-butyrolactones were obtained by hydrolyzing the alkylation products, with %e.e. being up to 89 percent.
Eleven (S) - (-) - bishydrocarbyl- (1-alkanoylpyrrolidin-2-yl) -methanol derivatives of three types were synthesized from L-proline, asymmotropic selective alkylation products were obtained by LDA treatment and alkylation using methyl 2-bromoethyl ether , and three types of chiral α-substituted-γ-butyrolactones were obtained by hydrolyzing the alkylation products, with% ee being up to 89 percent.
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