STRUCTURE OF NEODYMIUM TRINITRATE WITH DIPHENYL SULFOXIDE LIGANDS, Nd(N0_3)_3·[(C_6H_5SO]_4

• 出 处: 结构化学
• 发表日期: 1986年02期
• 关键词: triclinic coordinated benzene C_6H_5SO N0_3 Nd 七八 refine diagonal sulfoxide

Mr=2278, triclinic, Pl, a=11.154(1), b=14.310(2), c=17.295(2) A, α=84.09(1)°, β=72.97(1)°, r=69:37(1)°, V=2470.2(5)A3, Z=2; 2(MoKα)=12.9cm-1 F(000)=1154, Dx=1.53 g/cm3, room temperature. The final R=0.039, Rw=0.039 with wt=1, S=2.57 for 5710 independent reflections with | Fα|≥2.5σ(F0). The molecular configuration of the Nd-complex is similar to those of the Sm-complex and Pr-complex except for the difference in distances between central metal and the coordinated oxygen atoms.

Mr = 2278, triclinic, Pl, a = 11.154 (1), b = 14.310 (2), c = 17.295 (2) A, α = 84.09 (1) °, β = 72.97 37 (1) °, V = 2470.2 (5) A3, Z = 2; 2 (MoKα) = 12.9 cm -1 F (000) = 1154, Dx = 1.53 g / cm 3, room temperature. The molecular configuration of the Nd-complex is similar to those of the Sm-complex and Pr-complex except for the (R) = 0.039 with wt = 1, S = 2.57 for 5710 independent reflections with | Fα | difference in distances between central metal and the coordinated oxygen atoms.