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The hydro(solvo)thermal reactions of cobalt powder or its chloride with 2,5- pyridine dicarboxylic acid (H2PYDC) yielded two new complexes: [Co(II)2(PYDC)2(H2O)2- (H2O)4]n 1 and {Co(II)[NH2(CH3)2]2(PYDC)2}n 2. It is observed that the reactive solvents result in different connectivity modes of ligand and diverse dimensional extension of crystal structures. The correlation between structure and magnetic property will be discussed in this paper. Crystal data for 1: space group P1, a = 7.0419(17), b = 8.937(2), c = 9.6182(19) ?, α = 91.532(4), β = 99.869(10), γ = 107.889(11)o, V = 565.5(2) ?3, Z = 1, Dc = 1.845 g/cm3, μ = 1.56 mm-1, F(000) = 322 , R = 0.0505 and wR = 0.1580; and those for 2: space group C2/c, a = 14.9075(6), b = 8.2523(3), c = 16.9643(2) ?, β = 100.982(2)o, V = 2048.75(11) ?3, Z = 4, Dc = 1.560 g/cm3, μ = 0.892 mm-1, F(000) = 996, R = 0.0443 and wR = 0.1134.
The hydro (solvo) thermal reactions of cobalt powder or its chloride with 2,5- pyridine dicarboxylic acid (H2PYDC) yielded two new complexes: [Co (II) 2 (PYDC) 2 (H2O) 2- 1 and {Co (II) [NH2 (CH3) 2] 2 (PYDC) 2} n 2. It is observed that the reactive solvents result in different connectivity modes of ligand and diverse dimensional extensions of crystal structures. The correlation between structure and a = 7.0419 (17), b = 8.937 (2), c = 9.6182 (19) ?,? = 91.532 (4),? = 99.869 (10), γ = 107.889 (11) o, V = 565.5 (2)? 3, Z = 1, Dc = 1.845 g / cm3, μ = 1.56 mm-1, F and those for 2: space group C2 / c, a = 14.9075 (6), b = 8.2523 (3) and c = 16.9643 (2) ?,? = 100.982 (2) o and V = 2048.75 )? 3, Z = 4, Dc = 1.560 g / cm3, μ = 0.892 mm-1, F (000) = 996, R = 0.0443 and wR = 0.1134.