Recent advances in catalytic asymmetric hydrogenation:Renaissance of the monodentate phosphorus liga

• 作 者: GUO Hongchao DING Kuiling Dai
• 机 构: State Key Laboratory of Organometallic Chemistry
• 出 处: 科学通报（英文版）
• 发表日期: 2004年期
• 关键词: chiral phosphorus ligands monodentate ligands asymmetric catalysis hydrogenation

The history for the development of chiral phosphorus ligands in catalytic asymmetric hydrogenation is briefly highlighted. This review focuses on the recent advances in the synthesis of the monodentate phosphorus ligands and their applications in catalytic asymmetric hydrogenation. The examples highlighted in this article clearly demonstrated the importance and advantages of monodentate phosphorus ligands, which had been ignored for 30 a and experienced a renaissance at the very beginning of this millennium, particularly in the area of asymmetric hydrogenation.