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A dinuclear complex [DyFe(CN)6(DMF)4(H2O)3] @ 1.25H2O (DMF = N, N-dimethylformamide) 1 based onthe cyanide as linkage was prepared and structurally characterized by X-ray single-crystal structure analysis. TheDy (Ⅲ) ion is eight coordinations in a square-