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The Zr-H bond of zirconocene hydridochloride was heterolyzed at room temperature by five compounds containing nitrogen and hydroxyl group to give Cp(Q)2ZrCl(1) (Cp = cyclopentadienyl and Q = 8-quinolinoyl ) , Cp (Q-Me )2ZrCl (2) , Cp(5,7-Br2Q)2ZrCl(3), Cp