【摘 要】
：
The Bunsen reaction is the center reaction for both the sulfur–iodine water splitting cycle for hydro-gen production and the novel hydrogen sulfide splitting cycle for hydrogen and sulfuric acid production from the sulfur-containing gases. This paper revi
【机 构】
：
Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan
论文部分内容阅读
The Bunsen reaction is the center reaction for both the sulfur–iodine water splitting cycle for hydro-gen production and the novel hydrogen sulfide splitting cycle for hydrogen and sulfuric acid production from the sulfur-containing gases. This paper reviews the research progress of the Bunsen reaction in re-cent 10–15 years. Researches were initially focused on the optimization of the operating conditions of the conventional Bunsen reaction requiring excessive water and iodine to improve the products separa-tion efficiency and to avoid the side reactions and iodine vapor deposition. Alternative methods including electrochemical methods, precipitation methods, and non-aqueous solvent methods had their respective advantages, but still faced challenges. In development of the technology of H 2 S splitting cycle, dissolv-ing iodine in toluene solvent could render the Bunsen reaction to occur with the flowable I 2 stream at ambient temperature such that the side reactions and iodine vaporization can be avoided and the corro-sion hazard lessened. It also prevented the Bunsen reaction from using excessive iodine and water. The products from the Bunsen reaction including HI, H 2 SO4 , H 2 O, and toluene could be directly electrolyzed.
其他文献
For constructing next-generation lithium-ion batteries with advanced performances, pursuit of high-capacity Li-rich cathodes has caused considerable attention. So far, the low discharge specific capacity and serious capacity fading are strangling the deve
Supercapacitors,with ultrahigh power density,superior rate capability,long-term cyclability,and exceptional safety,are regarded as one highly competitive candidate of electrochemical energy storage devices,filling the gap between batteries and conventiona
The emergence of hybrid organic-inorganic metal halide perovskite solar cells (PSCs) causes a breakthrough in tihe solar technology recently due to its superior optoelectronic properties and the low-cost fabrication processes.The dramatic enhancement in p
Exploring inexpensive and efficient bifunctional electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is critical for rechargeable metal-air batteries.Herein,we report a new 3D hierarchical sulfur and nitrogen co-doped
Vanadium flow battery (VFB) is a fast going and promising system for large-scale stationary energy storage,However,drawbacks such as low power density and narrow temperature window caused by poor catalytic activity of graphite felt (GF) electrodes limit i
Herein,we report the design and synthesis of three new D-A type metal-free carbazole based dyes (S1-3) as effective co-sensitizers for dye-sensitized solar cell (DSSC) sensitized with Ru(Ⅱ) complex (NCSU-10).In this new design,the electron rich carbazole
The mixture of (2NaBH4 + MnCl2) was ball milled in a magneto-mill.No gas release was detected.The XRD patterns of the ball milled mixture exhibit only the Bragg diffraction peaks of the NaCl-type salt which on the basis of the present X-ray diffraction re
Through targeted and reproducible electrochemical treatment of glassy carbon electrodes,investigations have been carried out on the electrochemical behaviour of the oxidation of V2+,VO2+ and the reductions of VO2+,VO2+ and V3+ in order to pretreat electro
Many photocatalytic reactions such as CO2 reduction and N2 fixation are often limited by the activation of some key molecules.Defects in solid materials can robustly introduce coordinately unsaturated sites to serve as highly active sites for molecular ch
By designing and fabricating thin film electronic devices on a flexible substrate instead of more commonly used rigid substrate,flexible electronics produced has opened a field of special applications.In this article,we first reviewed available products t