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根据热动力学基本原理,推导出了连续一级反应热动力学自函数递推方程,从而建立了一种新的连续一级反应的热动力学研究法——自函数回归法.应用该法分别研究了丁二酸二乙酯和邻苯二甲酸二乙酯皂化反应的热动力学.
According to the basic principle of thermodynamics, the self-function recursion equation of continuous first-order reaction kinetic was deduced, and a new thermokinetic study method of continuous first-order reaction-self-function regression method was established. The thermodynamics of saponification of diethyl succinate and diethyl phthalate were studied respectively.