Synthesis, Crystal Structure and Photoluminescent Property of a 3D Hydrogen-bonded Supramolecular Co

• 作 者: 岳呈阳 江飞龙 袁大强 陈莲 吴明燕 洪茂椿
• 机 构: State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matte
• 出 处: 结构化学
• 发表日期: 2008年04期
• 关键词: hydrothermal monoclinic Hydrogen acetic bonds covalent bonded stacking struc dif

The title compound, [Pd(2,2’-bipy)2](H3adip)2·4H2O, was synthesized via the hydrothermal reaction of PdCl2 with 5-aminodiacetic isophthalic acid (H4adip) in an acetic acid water solution. It was characterized by elemental analysis and infrared spectrum. Crystal data for C44H44N6O20Pd: monoclinic, space group P21/n, a = 11.0674(2), b = 9.9716(2), c = 20.5770(3), β = 92.7300(3)°, V = 2268.29(7) 3, Z = 2, Mr = 1083.25, Dc = 1.586 g/cm3, F(000) = 1112, μ = 0.499 mm-1, λ(MoKα) = 0.71073 , T = 293(2) K, 2θmax = 51.38o, GOOF = 1.067, R = 0.0268 and wR = 0.0710 for 3770 reflections with I > 2σ(I). X-ray diffraction studies reveal that the title compound has an interesting 3D microporous architecture via hydrogen bonds with the cations located inside the channel.

The title compound, [Pd (2,2’-bipy) 2] (H3adip) 2.4H2O, was synthesized via the hydrothermal reaction of PdCl2 with 5-aminodiacetic isophthalic acid (H4adip) in an acetic acid water solution a = 11.0674 (2), b = 9.9716 (2), c = 20.5770 (3) , β = 92.7300 (3) °, and the mass spectrum for the C44H44N6O20Pd: monoclinic space group P21 / V = 2268.29 73 Z = 2 Mr = 1083.25 Dc = 1.586 g / cm3 F 000 = 1112 μ = 0.499 mm -1 λ MoKα = 0.71073  T = 293 (7) X-ray diffraction studies have shown that the title compound has an interesting 3D microporous architecture via hydrogen bonds (2) K, 2θmax = 51.38o, GOOF = 1.067, R = 0.0268 and wR = 0.0710 for 3770 reflections with I> 2σ with the cations located inside the channel.