A New Bis-（As3O6） Capping 6-Molybdonickelate Complex：Preparation and Characterization of [Ni（en）2（H2

• 作 者: WU Qiang HE Jie HAN Qiu-Xia YA
• 机 构: MedicalSchoolHenanUniversity,BasicExperimentTeachingCenter,InstituteofMolecularandCrystalEngineering
• 出 处: 结构化学
• 发表日期: 2010年8期
• 关键词: 水热合成 分析表征 封盖 镍 制备 复杂构造 红外光谱 射线衍射 polyoxometalate hydrothermal synthesis crysta
• 基金项目: Supported by the National Natural Science Foundation of China （20771034） and Natural Science Foundation of Henan Province （2009A150003）

A new complex constructed from a unit with two As3O6 rings capping Anderson-type moieties,[Ni(en)2(H2O)2]2[(NiO6)Mo6O18(As3O3)2]·2H2O(1,en = ethylenediamine),has been hydrothermally synthesized and characterized by IR,single-crystal X-ray diffraction