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The organic-inorganic hybrid complex with formula [(CuL)2Cu3(μ-1,1-N3)4(ClO4)2],complex 1,{CuL,[5,6:14,15-dibenzo-1,4,8,12-tetraazacyclopentadeca-7,13-diene-2,3-dione(2-)]copper(II)},has been synthesized and structurally determined. The crystals of complex 1 crystallize in the triclinic system with space group P1,a=0.92983(12) nm,b=1.09644(14) nm,c=1.27396(16) nm,α=70.782(2)°,β=86.266(2)°,γ=78.284(2)°. In this com-plex,the five copper ions are bridged by macrocyclic oxamide groups and azido. Furthermore,C―H···O hydrogen bond interactions link the pentanuclear fragments to form a 2D supramolecular architecture.
The organic-inorganic hybrid complex with formula [(CuL) 2Cu3 (μ-1,1-N3) 4 (ClO4) 2], complex 1, {CuL, [5,6: 14,15-dibenzo- 8,12-tetraazacyclopentadeca-7,13-diene-2,3-dione (2 -)] copper (II)}, has been synthesized and structurally determined. The crystals of complex 1 crystallize in the triclinic system with space group P1, a = 0.92983 (12) nm, b = 1.09644 (14) nm, c = 1.27396 (16) nm, α = 70.782 (2) °, β = 86.266 (2) ° and γ = 78.284 (2) °. com-plex, the five copper ions are bridged by macrocyclic oxamide groups and azido. Furthermore, C-H · O hydrogen bond interactions link the pentanuclear fragments to form a 2D supramolecular architecture.