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  5. Mn(Ⅲ)-mediated radical reaction of 2-isocyano-6-alkenyl(alkynyl) benzonitriles with arylboronic acid

Mn(Ⅲ)-mediated radical reaction of 2-isocyano-6-alkenyl(alkynyl) benzonitriles with arylboronic acid

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：jbajba321
【摘 要】
：
A Mn(Ⅲ) mediated radical reaction of new designed multi-functionalized 2-isocyano-6-alkenyl(alkynyl) benzonitriles with arylboronic acids has been developed. T
【作 者】
：
Pei Xu Yi-Ming Zhu Xin-Yu Liu Xiao-Zhou Zhou Shun-Yi Wang Shun-Jun Ji 
【机 构】
：
Key Laboratory of Organic Synthesis of Jiangsu Province,College of Chemistry,Chemical Engineering an
【出 处】
：
中国化学快报（英文版）
【发表日期】
：
2021年1期
【关键词】
：
2- Isocyano-6-alkenyl(alkynyl)benzonitriles Arylboronic acids Pyrroloisoquinolin 
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A Mn(Ⅲ) mediated radical reaction of new designed multi-functionalized 2-isocyano-6-alkenyl(alkynyl) benzonitriles with arylboronic acids has been developed. This reaction provides a method for the synthesis of pyrroloisoquinoline derivatives through the formation of two C--C bonds and one C--N bond via radical cascade cyclization in one step.
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